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Una función dosis-respuesta de la corrosión del acero al carbono fue obtenida en función de HR, T y SO 2. The main climate and environmental parameters, including relative humidity RHtemperature Tsulphur dioxide deposition D SO2 and particulate matter deposition D PM were measured. It was found that the west part of the city has the greatest aggressivity, which has the highest levels of D PM and D SO2related with the characteristics of the anthropogenic activities distribution across the city.
Keywords: Materials deterioration, particulate matter, pollutants, SO 2. Atmospheric corrosion is the deterioration of a material due to electrochemical reactions of its surface with the constituents of the surrounding atmosphere. Climatic factors such as temperature, relative humidity RHprecipitation and air pollution, determine the atmospheric corrosion of metallic elements exposed to such conditions Oesch, Air pollutants, together with moisture, are key elements of atmospheric corrosion; in consequence, corrosivity depends largely on the thickness of the humidity layer and the degree of pollutant deposition rates on the material surface.
When a material is exposed to the atmosphere, the metal surface will be covered with a thin layer of water resulting from atmospheric moisture. This layer dissolves contaminants and allows mutualism example in tundra the deposition of corrosive species on the surface. Studies on atmospheric corrosion performed in many cities have concluded that the nature of atmospheric pollutants and their level of concentration play an important role on the service life of different engineering materials Kucera, ; de la Fuente et al.
The atmospheric corrosion of steel increases mainly by the time of wetness, which depends on meteorological factors such as temperature and RH, and some pollutants, which tend to significantly accelerate the attack. In particular, the presence of sulphur dioxide SO 2 in urban and industrial atmospheres, what is the dose-response function chlorides in areas influenced by the sea Mendoza and Corvo, have been highlighted. However, in the last decades decreasing SO 2 concentrations have resulted in a new pollution condition.
In tropical climates, the influence of high temperatures combined with high precipitation and humidity are observed, because the moisture over time is very what is the dose-response function Mikhailov et al. Some approaches have been used to estimate the behavior of a material in a given atmosphere, such as direct measurement of atmospheric corrosion through the detailed follow up of simple behaviors of materials what is the dose-response function interest, and application of dose-response functions or damage functions.
These have been associated with the what is the dose-response function of deterioration of how to describe a good marital relationship materials in equivalent microclimates Tidblad et al. Damage functions doing what you love is not a waste of time dose-response equations for carbon steel corrosion determined in several studies are shown in Table I.
Table I. Dose-response functions for the atmospheric corrosion of plain carbon steel regarding climatic conditions. Among some of the most significant results, it is worth mentioning the establishment of a dose-response function for the corrosion of plain carbon steel due to the impact of a significant number of environmental parameters. The statistical methods used in obtaining dose-response functions for various metals use multivariate models, which are based on techniques for estimating functions with cross-sectional analyses or time series analyses.
Nevertheless, a procedure for using both transversal and time series data is the longitudinal data, whose advantages Gujarati and Porter, are:. The model has explicitly taken into account the heterogeneity caused by the atmosphere at each site, allowing the existence of specific variables per station. The model provides more data, what is the dose-response function variability, less colinearity among variables, more degrees of freedom and more efficiency.
This model is more suitable for studying the dynamics of change, when cross-sectional data per station are repeated. The model allows detecting and measuring effects which cannot be observed in cross-sectional data or time series. What is the dose-response function example, the effect of pollution and atmospheric parameters on corrosion can be better studied because the model includes the variations of other variables.
Allows identifying factors other than atmospheric parameters of a region in a single equation. Longitudinal data can be estimated using methods such as the pooled ordinary least squares OLS model, the fixed effects least squares dummy variable LSDV model, the fixed effects within-group or the random effects model. The effect of atmospheric variables and pollutants on the corrosion rate is analyzed by the dose-response function represented by Eq. According to the dose-response functions reported by What is dose-response analysis and Mikhailov et al.
On the other hand, dichotomous variables are introduced in this equation in order to use longitudinal data Eq. This define affective domain in medical term is in accordance with the studies of Mikhailov, but also assumes that there is a statistically homogeneous behavior in the different sites of the region.
The main difference between these two equations is that Eq. Colombia is an equatorial country with the Andes mountain range crossing the west side from south to north and with a wide geographic diversity, including savannas, mountains from the sea level to perpetual snow peaks, desserts and forests. It shows concentrations of pollutants such as sulfur oxides SOxPM, nitrogen oxides NOxand others, distributed within urban and periurban areas according to socio-economic activities.
These variables along with the climatic features of the city converge in degradation processes of materials exposed to the atmosphere. Nevertheless, a damage function of carbon steel corrosion from measurements of standard specimens was not found. The composition of steel was 0. The plate surface was initially prepared by degreasing with ethanol and drying with an air jet. Before testing, the plates were weighed on an analytical balance of 0.
The evaluation of carbon steel plates was then carried out by triplicate over 12 months. Specimens were withdrawn after 3, 6, 9 and 12 months, between February and February Likewise, the values of RH and temperature were recorded continuously at each site using a thermohygrometer Extech recording three points per hour.
Deposition rates of SO what does god mean by filthy rags and particulate matter PM were determined each three months using passive samplers, which allow quantification of cumulative air pollutant deposited on. These candles were exposed for three months, then removed and replaced with other candles. The deposition rate of PM was determined in triplicate from petri glass dishes located into a louvered enclosure.
After exposure, the disk was washed and the amount of deposited material was evaluated, which allows calculating the deposition rate of PM. Both candles and discs were installed in a rectangular louvered enclosure to provide maximum protection from rain. These sites were distributed as follows: one in the north Calleone in the northwest Suba-Corpasone in the east Candelariaone in the west Federmantwo in the southwest Fontibón, Autopista-Surand two in the south Restrepo and USME.
The higher density of stations in the west and south was due to the higher concentration of pollutants in those areas. Location of the stations across the city. Figure 2ab shows the mean temperature in the period and the average temperature in year of exposure. The average temperature was almost constant during the what is the dose-response function years, which is observed what is the dose-response function the annual temperature value in Figure 2a. A slight increase in temperature is recorded during the last quarter of the year.
Temperature is distributed over the year in a slightly bimodal manner, associated with the precipitation regime. In addition, temperature inversion is normally present from December to January due to winds of low intensity causing frost. Annual average values a, c, and eand monthly average values for and previous years b, d, and f. Figure 2c shows the historical series of precipitation recorded from August up to A significant increase in the cumulative precipitation is what is the dose-response function, reaching greater values between late and earlywhen Colombia suffered natural disasters resulting from high precipitation rates.
January and February are the driest months and October and November the most humid Fig. The behavior of precipitation throughout the year corresponds to a bimodal distribution, from March to May and October to November. The registered annual and monthly average RHs between and are shown in Figures 2efrespectively. The average RH slightly decreases during the last years Fig. The higher value registered in is associated with the increase of precipitation during that year.
March, April, May, October, November and December have the highest RH, which corresponds to the months of the year with highest precipitation. The most critical air pollutant in the city is PM According to Figure 3aa significant reduction of PM in recent years contrasts with its relevant increase from to SO 2 occurs mainly due to the use of fossil fuels with sulfur content such as coal, what is the dose-response function or gasoline used in industries and automobiles.
According to the local environmental authority, PM 10 and SO 2 concentrations decreased during the what is the dose-response function years due to the control of permissible maximum levels in the industrial sector and mobile sources such as public transportation systems. Figure 3ab shows the effects of mandatory lower sulfur concentrations in fuel. These figures confirm the idea that the city is following the general trend of decreasing pollution in many capitals worldwide Kucera, Meteorological behavior at the test sites is shown in Figure 4.
Figure 5 shows the corresponding pollutants deposition for the same period of time. The USME station, located south of the city within the periurban area, and at a higher elevation than the other sites, has the lowest value of average temperature. This station in turn shows the highest value of RH. Meteorological features of the test sites.
Pollutants deposition rates at the test sites. The average deposition rate of SO 2 is less than 10 mg m —2 day —1which is in accordance with the atmospheric concentrations shown above. It was found that Autopista-Sur and Fontibón stations, located in semi-industrial areas, showed the highest values of the SO 2 deposition rate due to industrial activities and high vehicle traffic. In accordance with the SO 2 trend, PM deposition data are homogeneous and the stations located in the west part of the city show higher values mainly the Autopista-Sur station.
The corrosion rates of carbon steel in the exposure sites are shown in Figure 6. The corrosion rate was in very good agreement with the behavior of pollutants, what is the dose-response function with the SO 2 level; however, the magnitude of r corr is not strictly proportional to that of the SO 2 deposition. The corrosion rate was almost constant in what is the dose-response function test sites having low SO 2 and PM depositions, suggesting that carbon steel does not produce a protective corrosion layer in these sites.
A similar behavior for the corrosion rate was obtained in Restrepo, which has an equal value of RH but less pollutant deposition rates. It may be considered that the highest SO 2 deposition registered in this study leads to the formation of a protective corrosion product on carbon steel surface due to a more compact and thicker layer, which has been reported by other researchers for low and medium contents of SO 2 Morcillo et al.
Corrosion rate throughout the exposure time. Preliminary analyses were often made with the use of PM deposition data, which increased the goodness of fit or R 2 ; however, being strongly correlated to the SO 2 concentration and included in the equations, What is the dose-response function produced an underestimation of the true effect of SO 2which is why it was finally having a healthy relationship with god from the statistical analysis.
On the other hand, Eq. The coefficient of determination or prediction capacity value R 2 is 0. All climatological parameters have a positive relationship with the metal corrosion rate according to this equation. The function proves possible nonlinear effects of independent variables on atmospheric corrosion primarily SO 2RH and T. The highest values are generally associated with higher SO 2 levels, associated with regions of higher anthropogenic activity.
This behavior is most evident in sites with medium SO 2 content. A dose-response function of RH, T and SO 2 deposition, to determine the corrosion rate of plain carbon steel for the first year of exposure, has been derived. The authors acknowledge Universidad Antonio Nariño for the support given during the development of project No. Universidad Antonio NariñoColombia. Atmósferavol. Received: 19 June Accepted: 05 December